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Browsing by Subject "(+)-epi-cytoxazone"
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Publication A short and efficient asymmetric synthesis of (±)-epi-cytoxazone from cis-(1R,2S,5R)-menthyl 4-methoxyphenylglycidates(Springer, 2014-12) Er, Mustafa; Coşkun, Necdet F.; Uludağ Üniversitesi/Fen Edebiyat Fakültesi/Kimya Bölümü.; B-1200-2012; 7004177880The racemic epi-cytoxazone was synthesized, starting from p-anisaldehyde, in five steps and 48% overall yield. An efficient synthesis of azido alcohols has been achieved by regioselective ring opening of glycidates using NaN3 in MeOH-H2O. The key step of the process is reductive cyclization of azide carbonates by Zn-TMSCl.