Person: OSMAN, BİLGEN
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OSMAN
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BİLGEN
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Publication Superhydrophobic surface based on cross-linked polymer(Iop Publishing Ltd, 2019-05-01) Osman, Bilgen; OSMAN, BİLGEN; Aydemir, Tuğba Gün; Bursa Uludağ Üniversitesi/Mühendislik Fakültesi; 0000-0001-8406-149X; ABF-4791-2020The aim of this study was to prepare a superhydrophobic surface by coating poly(divinylbenzene-N-methacryloyl-amido-L-phenylalanine ethyl ester) [poly(DVB-MAPA)] cross-linked polymer onto a glass surface. N-methacryloyl-amido-L-phenylalanine ethyl ester (MAPA) and 1, 4-divinylbenzene (DVB) were used as a monomer and a cross-linker, respectively. The polymerization mixture was dispersed in 1, 4 butanediol (BDO) for phase separation and polymerized on the glass surface. The superhydrophobic surface was characterized with Fourier transform infrared spectroscopy (FTIR), x-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and contact angle measurements. The effect of the composition of a polymerization mixture on hydrophobicity was investigated by varying the cross-linker to monomer mol ratio. Additionally, the influence of the composition of monomer/BDO mixtures was determined. The prepared poly(DVB-MAPA) surface showed a superhydrophobicity with a high water contact angle (WCA) of 162 degrees and a low sliding angle (SA) of 7 degrees . Moreover, the poly(DVB-MAPA) surface has a good chemical, thermal and daylight stability.Publication Molecularly imprinted solid-phase extraction sorbent for selective determination of melatonin(Elsevier, 2021-07-30) Esen, Elif; Osman, Bilgen; Demir, M. Nalan; OSMAN, BİLGEN; Bursa Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü; 0000-0001-8406-149X; ABF-4791-2020In this study, melatonin (MLT)-imprinted poly (ethylene glycol dimethacrylate-N-methacryloyl-L-tryptophan methyl ester) [MLT-PEMATrp] microbeads were prepared for solid phase extraction (SPE) of melatonin (MLT) from edible plants prior to high performance liquid chromatography (HPLC) analysis. The microbeads were prepared via molecular imprinting technique by using MLT as a template. The MLT-PEMATrp microbeads were characterized by using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), thermal gravimetic analysis (TGA), N2 adsorption/desorption isotherms and swelling test. The parameters such as adsorption time, temperature, adsorbent amount, pH and ionic strength were detailedly optimized to increase the effciency of MLT adsorption procedure. The adsorption properties of MLT onto the MLT-PEMATrp microbeads (MIP) and non-imprinted PEMATrp microbeads (NIP) were investigated to show the effectiveness of imprinting. MIP showed higher adsorption capacity for MLT (QMIP = 207.71 mg g-1) than NIP (QNIP = 12.15 mg g-1). The relative selectivity coefficients calculated for serotonin (3.41) and L-tryptophan (5.94) indicated that MLT-PEMATrp microbeads exhibit significantly high selectivity for MLT. The microbeads were used for SPE of MLT from Linden (Tilia tomentosa), fennel (Foeniculum Vulgare), sage (Salvia officinalis) and chamomilla (Matricaria chamomilla) samples prior to HPLC analysis. The recoveries of MLT in the samples were in the range of 90-103.4%. The SPE method had a limit of detection (LOD) in the range of 0.026-0.094 mu g mL-1. The MLTPEMATrp microbeads was very effective for SPE of MLT.Publication Adsorption of cinnabarinic acid from culture fluid with magnetic microbeads(Wiley, 2016-02-01) Sarıkaya, Aslı Göçenoğlu; Osman, Bilgen; Kara, Ali; Pazarlıoğlu, Nurdan; Besirli, Necati; GÖÇENOĞLU SARIKAYA, ASLI; OSMAN, BİLGEN; KARA, ALİ; Besirli, Necati; Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü,; 0000-0002-7161-7003; 0000-0001-8406-149X; 0000-0003-2457-6314; AAC-6901-2020; ABF-4791-2020; JXW-6168-2024; AAG-6271-2019In this study, antimicrobial pigment cinnabarinic acid (CA) was produced from Pycnoporus cinnabarinus in laboratory-scale batch cultures. Magnetic poly(ethylene glycol dimethacrylate-N-methacryloyl-l-tryptophan methyl ester) [m-poly(EGDMA-MATrp)] beads (average diameter = 53-103 mu m) were synthesized by copolymerizing of N-methacryloyl-l-tryptophan methyl ester (MATrp) with ethylene glycol dimethacrylate (EGDMA) in the presence of magnetite (Fe3O4) and used for the adsorption of CA. The m-poly(EGDMA-MATrp) beads were characterized by N-2 adsorption/desorption isotherms (Brunauer Emmet Teller), X-ray photoelecron spectroscopy, scanning electron microscopy, infrared spectroscopy, thermal gravimetric analysis, electron spin resonance and swelling studies. The efficiency of m-poly(EGDMA-MATrp) beads for separation of CA from culture fluid was evaluated. The effects of pH, initial concentration, contact time and temperature on adsorption were analyzed. The maximum CA adsorption capacity of the m-poly(EGDMA-MATrp) beads was 272.9mgg(-1) at pH7.0, 25 degrees C. All the isotherm data can be fitted with the Langmuir, Freundlich and Dubinin-Radushkevich isotherm models. The adsorption process obeyed pseudo-second-order kinetic model. Thermodynamic parameters H = 5.056kJmol(-1), S = 52.44JK(-1)mol(-1) and G = -9.424kJmol-(1) to -11.27kJmol-(1) with the rise in temperature from 4 to 40 degrees C indicated that the adsorption process was endothermic and spontaneous.