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A short and efficient asymmetric synthesis of (±)-epi-cytoxazone from cis-(1R,2S,5R)-menthyl 4-methoxyphenylglycidates

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dc.contributor.authorEr, Mustafa
dc.contributor.buuauthorCoşkun, Necdet F.
dc.contributor.departmentUludağ Üniversitesi/Fen Edebiyat Fakültesi/Kimya Bölümü.tr_TR
dc.contributor.researcheridB-1200-2012tr_TR
dc.contributor.scopusid7004177880tr_TR
dc.date.accessioned2024-01-16T06:46:45Z
dc.date.available2024-01-16T06:46:45Z
dc.date.issued2014-12
dc.description.abstractThe racemic epi-cytoxazone was synthesized, starting from p-anisaldehyde, in five steps and 48% overall yield. An efficient synthesis of azido alcohols has been achieved by regioselective ring opening of glycidates using NaN3 in MeOH-H2O. The key step of the process is reductive cyclization of azide carbonates by Zn-TMSCl.en_US
dc.identifier.citationCoşkun, N. F. ve Er, M. (2014). "A short and efficient asymmetric synthesis of (±)-epi-cytoxazone from cis-(1R,2S,5R)-menthyl 4-methoxyphenylglycidates". Chemistry of Natural Compounds, 50(6), 1071-1074.en_US
dc.identifier.endpage1074tr_TR
dc.identifier.issn0009-3130
dc.identifier.issn1573-8388
dc.identifier.issue6tr_TR
dc.identifier.scopus2-s2.0-84922105242tr_TR
dc.identifier.startpage1071tr_TR
dc.identifier.urihttps://doi.org/10.1007/s10600-014-1161-z
dc.identifier.urihttps://link.springer.com/article/10.1007/s10600-014-1161-z
dc.identifier.urihttps://hdl.handle.net/11452/39045
dc.identifier.volume50tr_TR
dc.identifier.wos000345771400023
dc.indexed.pubmedPubMeden_US
dc.indexed.wosSCIE
dc.indexed.wosIC
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.collaborationYurt içitr_TR
dc.relation.journalChemistry of Natural Compoundsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergitr_TR
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject(±)-epi-cytoxazoneen_US
dc.subjectZn-TMSCl reductionen_US
dc.subject4-methoxyphenylglycidateen_US
dc.subjectDarzen epoxidationen_US
dc.subjectAzidesen_US
dc.subjectStereoselective-synthesisen_US
dc.subjectCytokine modulatoren_US
dc.subject(+)-epi-cytoxazoneen_US
dc.subjectCytoxazoneen_US
dc.subject(-)-cytoxazoneen_US
dc.subjectPharmacology & pharmacyen_US
dc.subjectChemistryen_US
dc.subject.scopusCytoxazone; Ester; Stereochemistryen_US
dc.subject.wosChemistry, medicinalen_US
dc.subject.wosChemistry, organicen_US
dc.titleA short and efficient asymmetric synthesis of (±)-epi-cytoxazone from cis-(1R,2S,5R)-menthyl 4-methoxyphenylglycidatesen_US
dc.typeArticleen_US
dc.wos.quartileQ4
dspace.entity.typePublication

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