Development and application of a solid phase extraction method for the determination of phthalates in artificial saliva using new synthesised microspheres

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dc.contributor.buuauthorOsman, Bilgen
dc.contributor.buuauthorÖzer, Elif Tumay
dc.contributor.buuauthorBeşirli, Necati
dc.contributor.buuauthorGüçer, Şeref
dc.contributor.departmentUludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Anabilim Dalı.tr_TR
dc.contributor.orcid0000-0003-0610-2019tr_TR
dc.contributor.researcheridABF-4791-2020tr_TR
dc.contributor.researcheridAAI-3137-2021tr_TR
dc.contributor.scopusid15221651200tr_TR
dc.contributor.scopusid37047586000tr_TR
dc.contributor.scopusid6507924888tr_TR
dc.contributor.scopusid36849130600tr_TR
dc.date.accessioned2022-10-17T13:00:03Z
dc.date.available2022-10-17T13:00:03Z
dc.date.issued2013-06
dc.description.abstractThis paper describes a method for the determination of six phthalate esters (PEs) in artificial saliva using solid phase extraction (SPE) and gas chromatography-mass spectrometry (GC-MS). A new material was developed to isolate the PEs from artificial saliva. Poly(ethylene glycol dimethacrylate-N-methacryloyl-L-tryptophan methyl ester) (poly(EGDMA-MATrp)) microspheres (average diameter = 106-300 mu m) were synthesised and characterised. Several different parameters, such as pH, adsorption time and adsorbent amount, which affect SPE, were carefully optimised by central composite design (CCD). The best analytical conditions for the simultaneous determination of the analytes from a spiked artificial saliva sample were found to be a pH of 6.8, an adsorption time of 90 min, and an adsorbent amount of 1.8 g L-1, using dichloromethane as the elution solvent. These conditions were applied to study the migration of PEs found on various children's toys into saliva.en_US
dc.identifier.citationOsman, B. vd. (2013). "Development and application of a solid phase extraction method for the determination of phthalates in artificial saliva using new synthesised microspheres". Polymer Testing, 32(4), 810-818.en_US
dc.identifier.endpage818tr_TR
dc.identifier.issn0142-9418
dc.identifier.issn1873-2348
dc.identifier.issue4tr_TR
dc.identifier.scopus2-s2.0-84876927135tr_TR
dc.identifier.startpage810tr_TR
dc.identifier.urihttps://doi.org/10.1016/j.polymertesting.2013.03.017
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S0142941813000573
dc.identifier.urihttp://hdl.handle.net/11452/29125
dc.identifier.volume32tr_TR
dc.identifier.wos000320090700025
dc.indexed.scopusScopusen_US
dc.indexed.trdizinTrDizintr_TR
dc.indexed.wosSCIEen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.bapKUAP(F)-2012/58tr_TR
dc.relation.journalPolymer Testingen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergitr_TR
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMaterials scienceen_US
dc.subjectPolymer scienceen_US
dc.subjectPhthalateen_US
dc.subjectGas chromatography mass spectrometry poly(EGDMA-MATrp)en_US
dc.subjectSalivaen_US
dc.subjectCentral composite designen_US
dc.subjectChromatography-mass-spectrometryen_US
dc.subjectDiethyl phthalateen_US
dc.subjectActivated carbonen_US
dc.subjectAqueous-phaseen_US
dc.subjectEstersen_US
dc.subjectMicroextractionen_US
dc.subjectMigrationen_US
dc.subjectPlasticizersen_US
dc.subjectAdsorptionen_US
dc.subjectProductsen_US
dc.subjectAdsorptionen_US
dc.subjectAmino acidsen_US
dc.subjectDichloromethaneen_US
dc.subjectEsterificationen_US
dc.subjectEstersen_US
dc.subjectGas chromatographyen_US
dc.subjectMicrospheresen_US
dc.subjectPhase separationen_US
dc.subjectPotassium compoundsen_US
dc.subjectCentral composite designsen_US
dc.subjectGas chromatography-mass spectrometryen_US
dc.subjectPhthalatesen_US
dc.subjectpoly(EGDMA-MATrp)en_US
dc.subjectSalivaen_US
dc.subjectBody fluidsen_US
dc.subject.scopusEndocrine Disruptor; Phthalic Acid Bis(2 Ethylhexyl) Ester; Plasticizersen_US
dc.subject.wosMaterials science, characterization & testingen_US
dc.subject.wosPolymer scienceen_US
dc.titleDevelopment and application of a solid phase extraction method for the determination of phthalates in artificial saliva using new synthesised microspheresen_US
dc.typeArticle
dc.wos.quartileQ1 (Materials science, characterization & testing)en_US
dc.wos.quartileQ2 (Polymer science)en_US

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