Concomitant crystallization of Copper(II) sachharinato complexes with 2-methylpyrazine as a monomer and an one-dimensional polymer: Syntheses, crystal structures, spectroscopic and thermal properties
dc.contributor.author | Senel, Evrim | |
dc.contributor.author | Kazak, Canan | |
dc.contributor.buuauthor | Yilmaz, Veysel Turan | |
dc.contributor.department | Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü. | tr_TR |
dc.contributor.orcid | 0000-0002-2849-3332 | tr_TR |
dc.contributor.researcherid | L-7238-2018 | tr_TR |
dc.contributor.scopusid | 7006269202 | tr_TR |
dc.date.accessioned | 2024-04-03T08:43:34Z | |
dc.date.available | 2024-04-03T08:43:34Z | |
dc.date.issued | 2008-06-03 | |
dc.description.abstract | The reaction of [Cu(sac)(2)(H(2)O)(4)] center dot 2H(2)O with 2-methylpyrazine (mpyz) leads two complexes, concomitant crystallization of a mononuclear complex [Cu(sac)(2)(mpyz)(H(2)O)(2)] (1) and a polymeric complex [Cu(sac)(2)(mu-mpyz)](n) (2). Both complexes have been characterized by elemental analyses, magnetic measurements, FT-IR and ESR, TG-DTA and single-crystal X-ray diffraction analyses. Single-crystal X-ray analyses show that complex 1 consists of discrete molecules in which the copper(II) ions exhibits a square-pyramidal coordination geometry. The individual molecules of 1 are connected into a hydrogen-bonded chain structure, which is further assembled to form a three-dimensional network by pi-pi stacking interactions. Complex 2 is an 1D coordination polymer in which copper(II) centers are bridged by the mpyz ligand. The chains are further assembled to form two-dimensional frameworks by pi-pi and C-H center dot center dot center dot pi stacking interactions. | en_US |
dc.identifier.citation | Yılmaz, V. T. vd. (2008). "Concomitant crystallization of Copper(II) sachharinato complexes with 2-methylpyrazine as a monomer and an one-dimensional polymer: Syntheses, crystal structures, spectroscopic and thermal properties". Journal of Inorganic and Organometallic Polymers and Materials, 18(3), 407-413. | en_US |
dc.identifier.doi | https://doi.org/10.1007/s10904-008-9218-8 | |
dc.identifier.endpage | 413 | tr_TR |
dc.identifier.issn | 1574-1443 | |
dc.identifier.issue | 3 | tr_TR |
dc.identifier.scopus | 2-s2.0-46649086913 | tr_TR |
dc.identifier.startpage | 407 | tr_TR |
dc.identifier.uri | https://link.springer.com/article/10.1007/s10904-008-9218-8 | en_US |
dc.identifier.uri | https://hdl.handle.net/11452/40950 | |
dc.identifier.volume | 18 | tr_TR |
dc.identifier.wos | 000257374900012 | tr_TR |
dc.indexed.wos | SCIE | en_US |
dc.language.iso | en | en_US |
dc.publisher | Springer | en_US |
dc.relation.collaboration | Yurt içi | tr_TR |
dc.relation.journal | Journal of Inorganic and Organometallic Polymers and Materials | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi | tr_TR |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | 2-methylyrazine | en_US |
dc.subject | Coordination polymer | en_US |
dc.subject | Copper(II) complex | en_US |
dc.subject | One-dimensional chain | en_US |
dc.subject | Saccharinate | en_US |
dc.subject | Two-dimensional framework | en_US |
dc.subject | Magnetic-properties | en_US |
dc.subject | Dicyanamide n(cn)(2)(-) | en_US |
dc.subject | Superexchange mechanism | en_US |
dc.subject | Deprotonated saccharin | en_US |
dc.subject | Coordination polymers | en_US |
dc.subject | Substituted pyrazine | en_US |
dc.subject | Nitrate | en_US |
dc.subject | Pyz | en_US |
dc.subject | Perchlorate | en_US |
dc.subject | Isomerism | en_US |
dc.subject | Polymer science | en_US |
dc.subject.scopus | Complex; Palladium; 2-Phenylpyridine | en_US |
dc.subject.wos | Polymer science | en_US |
dc.title | Concomitant crystallization of Copper(II) sachharinato complexes with 2-methylpyrazine as a monomer and an one-dimensional polymer: Syntheses, crystal structures, spectroscopic and thermal properties | en_US |
dc.type | Article | en_US |
dc.wos.quartile | Q2 (Polymer science) | en_US |
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