Synthesis and characterization of one-dimensional coordination polymers, [M(sac)₂(mu-pyz)(H₂O)₂](n) [M=Zn(II), Cd(II), pyz =pyrazine, and sac = saccharinate]
dc.contributor.author | Şenel, Evrim | |
dc.contributor.author | Kazak, Canan | |
dc.contributor.buuauthor | Yılmaz, Veysel Turan | |
dc.contributor.department | Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü. | tr_TR |
dc.contributor.orcid | 0000-0002-2849-3332 | tr_TR |
dc.contributor.researcherid | L-7238-2018 | tr_TR |
dc.contributor.scopusid | 7006269202 | tr_TR |
dc.date.accessioned | 2024-04-03T10:46:32Z | |
dc.date.available | 2024-04-03T10:46:32Z | |
dc.date.issued | 2008 | |
dc.description.abstract | Two new coordination polymers, [M(sac)₂(mu-pyz)(H₂O)₂]n [M=Zn(II)(1), Cd(II)₂, pyz =pyrazine, and sac =saccharinate], have been prepared and characterized by elemental analysis, FTIR spectroscopy, thermal analysis and single crystal X-ray diffraction. Both complexes are isomorphous and crystallize in the triclinic P (1) over bar space group. The metal(II) ions are octahedrally coordinated by two sac, two aqua and two pyz ligands. The sac ligands are N-coordinated, while the pyz ligands are bridges between the metal centers, leading to one-dimensional linear chains. Intra-chain M-M separations in 1 and 2 are 7.218 and 7.498 angstrom, respectively. The individual chains are linked by strong OW-H center dot center dot center dot O(sac) hydrogen bonds into two-dimensional layers, which are further assembled into three-dimensional supramolecular networks by aromatic pi(sac)center dot center dot center dot pi(sac) stackings interactions. | en_US |
dc.description.sponsorship | Ondokuz Mayıs Üniversitesi | tr_TR |
dc.identifier.citation | Yılmaz, V. T. vd. (2008). "Synthesis and characterization of one-dimensional coordination polymers, [M(sac)₂(mu-pyz)(H₂O)₂](n) [M=Zn(II), Cd(II), pyz =pyrazine, and sac = saccharinate]". Journal of Coordination Chemistry, 61(16), 2675-2682. | en_US |
dc.identifier.doi | https://doi.org/10.1080/00958970801986783 | |
dc.identifier.endpage | 2682 | tr_TR |
dc.identifier.issn | 0095-8972 | |
dc.identifier.issue | 16 | tr_TR |
dc.identifier.scopus | 2-s2.0-46749095040 | tr_TR |
dc.identifier.startpage | 2675 | tr_TR |
dc.identifier.uri | https://www.tandfonline.com/doi/full/10.1080/00958970801986783 | en_US |
dc.identifier.uri | https://hdl.handle.net/11452/40960 | |
dc.identifier.volume | 61 | tr_TR |
dc.identifier.wos | 000257338400016 | tr_TR |
dc.indexed.wos | SCIE | en_US |
dc.language.iso | en | en_US |
dc.publisher | Taylor & Francis | en_US |
dc.relation.collaboration | Yurt içi | tr_TR |
dc.relation.journal | Journal of Coordination Chemistry | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi | tr_TR |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Coordination polymer | en_US |
dc.subject | Crystal structure | en_US |
dc.subject | One-dimensional chain | en_US |
dc.subject | Pyrazine | en_US |
dc.subject | Saccharinate | en_US |
dc.subject | Complexes | en_US |
dc.subject | Cadmium(II) | en_US |
dc.subject | Molecules | en_US |
dc.subject | Chemistry | en_US |
dc.subject.scopus | Complex; Palladium; 2-Phenylpyridine | en_US |
dc.subject.wos | Chemistry, inorganic & nuclear | en_US |
dc.title | Synthesis and characterization of one-dimensional coordination polymers, [M(sac)₂(mu-pyz)(H₂O)₂](n) [M=Zn(II), Cd(II), pyz =pyrazine, and sac = saccharinate] | en_US |
dc.type | Article | en_US |
dc.wos.quartile | Q3 (Chemistry, inorganic & nuclear) | en_US |
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