Publication:
5,5-Diethylbarbiturato complexes of copper(II) with (2-aminoethyl)piperidine, -pyrrolidine, and -morpholine: Syntheses, crystal structures, spectroscopic, and thermal properties

dc.contributor.authorBüyükgüngor, Orhan
dc.contributor.buuauthorAksoy, Mehmet Suat
dc.contributor.buuauthorYılmaz, Veysel Turan
dc.contributor.departmentFen Edebiyat Fakültesi
dc.contributor.departmentKimya Ana Bilim Dalı
dc.contributor.orcid0000-0002-2849-3332
dc.contributor.researcheridL-7238-2018
dc.contributor.scopusid8986297500
dc.contributor.scopusid7006269202
dc.date.accessioned2021-12-08T08:07:57Z
dc.date.available2021-12-08T08:07:57Z
dc.date.issued2009
dc.description.abstractThree new complexes, [Cu(barb)2(aepip)] center dot 0.5H2O (1), [Cu(barb)2(aepyrd)] (2), and [Cu(barb)2(aemrph)] (3), have been synthesized by reaction of 5,5-diethlybarbiturate anion (barb) with copper(II) in the presence of (2-aminoethyl)piperidine (aepip), -pyrrolidine (aepyrd), and -morpholine (aemrph). All complexes were characterized by elemental analysis, spectroscopic (IR and UV/Vis), thermal (DTA-TGA), and magnetic susceptibility measurements. X-ray single crystal diffraction shows that 1 and 2 are discrete mononuclear species, in which copper(II) is coordinated by two bidentate barb ligands and a chelating aepip or aepyrd, forming a square-pyramidal coordination geometry. Complexes 1 and 2 show unequal coordination of barb, one N-coordinate, and one bidentate. Complex 3 is also mononuclear, but copper(II) is square-planar with two N-coordinated barb and one bidentate aemorph. Molecules of 1-3 are bridged by strong hydrogen bonds to generate 1-D or 2-D supramolecular networks. Spectral and thermal data for 1-3 are in agreement with crystal structures.
dc.identifier.citationAksoy, M. S. vd. (2009). "5,5-Diethylbarbiturato complexes of copper(II) with (2-aminoethyl)piperidine, -pyrrolidine, and -morpholine: Syntheses, crystal structures, spectroscopic, and thermal properties". Journal of Coordination Chemistry, 62(20), 3250-3258.
dc.identifier.endpage3258
dc.identifier.issn0095-8972
dc.identifier.issue20
dc.identifier.scopus2-s2.0-69949108520
dc.identifier.startpage3250
dc.identifier.urihttps://doi.org/10.1080/00958970903051924
dc.identifier.urihttps://www.tandfonline.com/doi/full/10.1080/00958970903051924
dc.identifier.urihttp://hdl.handle.net/11452/23084
dc.identifier.volume62
dc.identifier.wos000269541900002
dc.indexed.wosSCIE
dc.language.isoen
dc.publisherTaylor & Francis
dc.relation.bapF-2008/56
dc.relation.collaborationYurt içi
dc.relation.journalJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subject(2-Aminoethyl)morpholine
dc.subject(2-Aminoethyl)piperidine
dc.subject(2-Aminoethyl)pyrrolidine
dc.subject5,5-Diethylbarbiturate
dc.subjectCopper(II)
dc.subjectMolecular-structure
dc.subjectLigands
dc.subjectChemistry
dc.subject.scopusThiobarbituric Acid; Barbiturates; DMV
dc.subject.wosChemistry, inorganic & nuclear
dc.title5,5-Diethylbarbiturato complexes of copper(II) with (2-aminoethyl)piperidine, -pyrrolidine, and -morpholine: Syntheses, crystal structures, spectroscopic, and thermal properties
dc.typeArticle
dc.wos.quartileQ3
dspace.entity.typePublication
local.contributor.departmentFen Edebiyat Fakültesi/Kimya Ana Bilim Dalı
local.indexed.atScopus
local.indexed.atWOS

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