Publication:
Photocatalytic degradation of chlothianidin: Effect of humic acids, nitrates, and oxygen

dc.contributor.authorKralj, M. B.
dc.contributor.authorMazur, D. M.
dc.contributor.authorLebedev, A. T.
dc.contributor.authorTrebse, P.
dc.contributor.buuauthorDilcan, E. G.
dc.contributor.buuauthorSalihoğlu, G.
dc.contributor.buuauthorSALİHOĞLU, GÜRAY
dc.contributor.departmentBursa Uludağ Üniversitesi/Mühendislik Fakültesi/Çevre Mühendisliği Bölümü.
dc.contributor.researcheridAAG-9399-2021
dc.date.accessioned2024-07-12T07:23:07Z
dc.date.available2024-07-12T07:23:07Z
dc.date.issued2019-12-01
dc.description.abstractThe use of neonicotinoid insecticides has been constantly revised because of their impact on bees, causing their decrease and bee malady. Unfortunately, because of the worldwide differences in pesticide regulation, chlothianidin is still allowed in European Union for greenhouse use and worldwide in some cases without any restictions. Lately, it was detected on soil particles and in raw and drinking waters. The preparation of drinking waters implies different purification processes, including chlorination, ozonation, and UV irradiation and nowadays advanced oxidation processes, including TiO2. The TiO2 photocatalytic degradation of chlothianidin in the presence of oxygen, nitrate, and humic acids was followed by kinetic studies, whereas the photoproducts formed were identified by liquid chromatography/tandem mass spectrometry. The efficiency of different set-ups of the photocatalytic degradation of chlothianidin was evaluated by the identification of photoproducts and bioluminescence inhibition of bacteria Vibrio fischeri. The results indicate that less harmful photoproducts are generated in the samples with added humic acids.
dc.description.sponsorshipSlovenian Research Agency - Slovenia P3-0388
dc.description.sponsorshipScholarship of the Republic of Slovenia scheme Mobility Grant (CMEPIUS)
dc.identifier.doi10.1134/S1061934819140077
dc.identifier.endpage1377
dc.identifier.issn1061-9348
dc.identifier.issue14
dc.identifier.startpage1371
dc.identifier.urihttps://doi.org/10.1134/S1061934819140077
dc.identifier.urihttps://hdl.handle.net/11452/43221
dc.identifier.volume74
dc.identifier.wos000510615500002
dc.indexed.wosWOS.SCI
dc.language.isoen
dc.publisherPleiades Publishing Inc
dc.relation.journalJournal Of Analytical Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectNeonicotinoid insecticides
dc.subjectAquatic chlorination
dc.subjectEnvironmental fate
dc.subjectMass-spectrometry
dc.subjectThiamethoxam
dc.subjectClothianidin
dc.subjectWater
dc.subjectTio2
dc.subjectPhotodegradation
dc.subjectContamination
dc.subjectNeonicotinoids
dc.subjectPhotocatalysis
dc.subjectTio2
dc.subjectChlothianidin
dc.subjectHumic acid
dc.subjectNitrates
dc.subjectHplc-ms/ms
dc.subjectScience & technology
dc.subjectPhysical sciences
dc.subjectChemistry, analytical
dc.subjectChemistry
dc.titlePhotocatalytic degradation of chlothianidin: Effect of humic acids, nitrates, and oxygen
dc.typeArticle
dspace.entity.typePublication
relation.isAuthorOfPublication76512d6e-0f48-4fcd-bf31-5be60d0790f7
relation.isAuthorOfPublication.latestForDiscovery76512d6e-0f48-4fcd-bf31-5be60d0790f7

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